A couple others come to mind but they aren't the official MTV videos...still, they're professionally shot and were better than most of the shit MTV was playing when it still played videos.
Metallica "Enter Sandman" from Russia in 1991. They played in front of over 1.5 million people on an old air force base or something. Soldiers were supposed to work security but you can see some in the crowd just rocking out. Helicopters flying over the crowd. This was wild.
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And then Pearl Jam "Porch" at PinkPop in the Netherlands in 1992.
It wasn't over a million people, but the crowd was still huge. The band's energy was insane (I wish they still played this this fast), and it'd be pretty nuts to be jamming out on the guitar and then all of a sudden you see your lead singer leaping off the camera rig into the crowd.
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Thinking back, before TRL there was still a nightly top-10 show in the early 90s. I remember Nirvana "Heart Shaped Box" and Meatloaf "I Would Do Anything For Love" were on it quite a bit. That Meatloaf video was cool.
Someone mentioned "Sabotage", yeah that was great. RHCP "Soul to Squeeze" was good. I remember being like 10 years old and digging the chick in the Billy Idol "Cradle of Love" video.
Oh, shit...Aerosmith "Cryin'" and "Amazing" were really cool.
Foo Fighters "Learn to Fly" was great, in a goofy way.
Tom Petty's videos were good... can't remember which one it was, but one had an Alice in Wonderland thing going on.
En Vogue "Never Gonna Get It" just had a cool look to it; black & white, but they were wearing all silver. And it was super super simple, but whenever I think back, every time, the first video that pops in my head is Sinead O'Connor covering "Nothing Compares". It was just on so damn often...but if I can remember it so well 30 years later, it had to be good.
I feel like the sweet spot was 1985 - 1995. Before that, videos were fairly simple, working out the kinks of what made cool videos. After that, too many people started using whatever the hell it's called, "fisheye" or something, where it's like zooming in through a peep hole (off the top of my head I'm thinking Jamiroquai and Missy Elliott).
But the more I think back, the more I realize it starts and ends with Michael Jackson. You could teach a PhD-level music video production course and only use his videos.